catena-Poly[[[diaquacopper(II)]-bis[μ-1,1′-(butane-1,4-diyl)diimidazole-κ2 N 3:N 3′]] dinitrate]
نویسندگان
چکیده
In the title compound, {[Cu(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Cu(II) ion lies on an inversion center and is six-coordinated in an octa-hedral environment by four N atoms from four different 1,1'-butane-1,4-diyldiimidazole ligands and two O atoms from the two water mol-ecules. Bridging by the ligands results in a ribbon structure. Adjacent ribbons are linked to the nitrate anions via O-H⋯O hydrogen bonds, forming layers. One nitrate O atom is disordered equally over two positions.
منابع مشابه
catena-Poly[[dichloridozinc(II)]-μ-[1,1′-(butane-1,4-diyl)diimidazole-κ2 N 3:N 3′]]
The title one-dimensional coordination polymer, [ZnCl(2)(C(10)H(14)N(4))](n), was synthesized by hydro-thermal methods from ZnCl(2) and 1,1'-(butane-1,4-di-yl)diimidazole. The Zn atom is coordinated by two chloride ions and two N atoms from two symmetry-independent organic ligands and shows a distorted tetra-hedral coordination geometry. The 1,1'-(butane-1,4-di-yl)diimidazole ligands are locate...
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متن کاملcatena-Poly[[dichloridozinc(II)]-μ-1,1′-(butane-1,4-diyl)diimidazole-κ2 N 3:N 3′]
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In the title coordination polymer, {[Ni(C(8)H(10)O(4))(C(10)H(14)N(4))]·0.25H(2)O}(n), the coordination of the Ni(II) ion is distorted octa-hedral. The 1,1'-(butane-1,4-di-yl)diimidazole ligand and the cyclo-hexane-1,4-dicarboxyl-ate dianion bridge metal centres, forming a two-dimensional (4,4) network. The network is consolidated by O-H⋯O hydrogen bonds between the statistically occupied water...
متن کاملPoly[μ-aqua-[μ-1,1′-(butane-1,4-diyl)diimidazole]bis(μ4-naphthalene-1,4-dicarboxylato)dicadmium(II)]
In the title compound, [Cd(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n), the coordination polyhedron around each Cd(II) ion is a distorted CdNO(5) octa-hedron. The water O atom has site symmetry 2 and the complete 1,1'-(butane-1,4-di-yl)diimidazole (L) ligand is generated by inversion. The naphthalene-1,4-dicarboxyl-ate and L ligands bridge the metal centres, forming a three-dimensional fram...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008